کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1410238 1501852 2009 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Syntheses, topological structures and physical properties of two 2D lanthanide–organic frameworks constructed from 5-nitroisophthalic acid
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Syntheses, topological structures and physical properties of two 2D lanthanide–organic frameworks constructed from 5-nitroisophthalic acid
چکیده انگلیسی

Two lanthanide–organic frameworks Pr2[(NIPH)3·3H2O]·H2O (1) and [Nd2(NIPH)3·3H2O]·H2O (2) were synthesized via the self-assembly of Ln(NO3)·6H2O (Ln = Pr or Nd) with 5-nitroisophthalic acid (H2NIPH) in the presence of imidazole under hydrothermal reactions. X-ray single-crystal diffraction analyses reveal that 1 and 2 are isomorphic and both exhibit an unprecedented 2D topological net. Compounds 1 and 2 both have a 3D supramolecular framework extended by hydrogen-bonding interactions between the adjacent layers. Furthermore, the magnetic behaviors for 1 and 2 in the temperature range of 2–300 K were investigated.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 938, Issues 1–3, 16 December 2009, Pages 111–116
نویسندگان
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