کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1410249 | 1501852 | 2009 | 7 صفحه PDF | دانلود رایگان |

Three new polymers, namely, {[Cd(TTTMB)(bdic2−)(H2O)]·H2O}n (1), {[Cd(TTTMB)(Hbtrc2−)(H2O)]·2H2O}n (2) and [Zn(TTTMB)(Hbtrc2−)(H2O)]n (3) based on a flexible tripodal ligand 1,3,5-tris(triazol-1-ylmethyl)-2,4,6-trimethylbenzene (TTTMB) have been synthesized by choosing H2bdic and H3btrc as auxiliary ligands under hydrothermal reaction (H2bdic = 1,3-benzenedicarboxylic acid and H3btrc = 1,3,5-benzenetricarboxylic acid). The structures of the polymers were determined by single-crystal X-ray diffraction analyses, and the results reveal that 1 and 2 exhibits a two-dimensional (4,4) network. While the crystal structure of 3 shows one-dimensional zigzag chain. Additionally, the solid-state fluorescent properties of these three polymers and ligand TTTMB were investigated at room temperature.
Journal: Journal of Molecular Structure - Volume 938, Issues 1–3, 16 December 2009, Pages 185–191