کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1410617 1501873 2008 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Molecular structure and vibrational spectra of 2-amino-5-methyl pyridine and 2-amino-6-methyl pyridine by density functional methods
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Molecular structure and vibrational spectra of 2-amino-5-methyl pyridine and 2-amino-6-methyl pyridine by density functional methods
چکیده انگلیسی

The Fourier transform Raman (3500–50 cm−1) and Fourier transform infrared (4000–400 cm−1) spectra of 2-amino-5-methylpyridine and 2-amino-6-methylpyridine have been measured in solid phase. The Fourier transform gas phase infrared spectra of 2-amino-5-methylpyridine and 2-amino-6-methylpyridine have also been measured. Density functional theory harmonic and anharmonic frequency calculations have been made. A complete vibrational assignments of the observed spectra of both molecules have been proposed. Geometric parameters have been compared with single crystal X-ray diffraction data of the molecule. The theoretical IR spectra of the title molecules have been constructed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 891, Issues 1–3, 26 November 2008, Pages 284–291
نویسندگان
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