کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1411709 | 1501875 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A new acenaphthenequinone-based calix[4]pyrrole: Synthesis, structure and anion binding study
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: A new acenaphthenequinone-based calix[4]pyrrole: Synthesis, structure and anion binding study A new acenaphthenequinone-based calix[4]pyrrole: Synthesis, structure and anion binding study](/preview/png/1411709.png)
چکیده انگلیسی
A new calix[4]pyrrole type anion receptor (1) containing two anti-symmetrically meso-situated acenaphthenequinone moieties has been constructed by a “one-pot” facile synthesis. The crystal structures of 1 and 1·F− complex were characterized by X-ray crystallography. The crystal of 1·F− complex witnessed that a CH group from the acenaphthenequinone participated in anion binding through CH…F hydrogen bond which was also conformed in solution by 1H NMR titration in CD2Cl2. The anion binding property of 1 was studied in CH2Cl2 using UV–vis spectrometry and the results reflected that it bound selectively with F− and Cl− ions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 889, Issues 1–3, 29 October 2008, Pages 279–285
Journal: Journal of Molecular Structure - Volume 889, Issues 1–3, 29 October 2008, Pages 279–285
نویسندگان
Wenzhi Yang, Zhenming Yin, Zhao Li, Jiaqi He, Jin-Pei Cheng,