کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1411831 | 1501900 | 2007 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Analytical solutions for the E ⊗ e dynamic Jahn–Teller problem in the strong coupling limit
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Analytical solutions for the E ⊗ e dynamic Jahn–Teller problem in the strong coupling limit Analytical solutions for the E ⊗ e dynamic Jahn–Teller problem in the strong coupling limit](/preview/png/1411831.png)
چکیده انگلیسی
Correct boundary conditions for wavefunctions in the E ⊗ e dynamic Jahn–Teller problem explicitly is considered to obtain approximate analytical solutions in the strong coupling limit. We demonstrate that the pseudorotational energy j2/(2g2), where g is the dimensionless vibronic coupling constant, and j total angular momentum: j = 1/2, 3/2, …, in the conventional strong coupling expression for the vibronic levels of the lower sheet is exact. However, it is found that in the conventional treatment a term of the order of 1/g2 is missing. The solutions for the upper sheet with correct boundary conditions gives those which are entirely different from the corresponding Slonczewski’s solutions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 838, Issues 1–3, 16 July 2007, Pages 8–12
Journal: Journal of Molecular Structure - Volume 838, Issues 1–3, 16 July 2007, Pages 8–12
نویسندگان
Tohru Sato, Liviu F. Chibotaru, Arnout Ceulemans,