کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1411920 | 1501909 | 2007 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Self-assembled carboxylate complexes of zinc, nickel and copper
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Self-assembled carboxylate complexes of zinc, nickel and copper Self-assembled carboxylate complexes of zinc, nickel and copper](/preview/png/1411920.png)
چکیده انگلیسی
A metallo-organic hybrid acid namely tetra-aquo bis-4-carboxy-N-phthaloylglycinato zinc(II) dihydrate is prepared and characterised. In this complex the hydrogen bonding by free carboxylic acid group and π–π interactions between the rings in crystal lattice contributes to the formation of self-assembled structure. A monomeric nickel complex from 2-carbomethoxy benzoic acid (L2H) and pyridine [Ni(L2)(py)3(H2O)2]L2 is prepared (where py = pyridine). This complex has ionic as well as monodentate carboxylates. It forms self-assembly by C–H⋯π as well as hydrogen-bonding interactions. The 2-carbomethoxy benzoic acid (L2H) forms dimeric copper complex [Cu2(L2)4(H2O)2]2H2O which has an extended chain structure through hydrogen-bond interactions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 827, Issues 1–3, 17 February 2007, Pages 44–49
Journal: Journal of Molecular Structure - Volume 827, Issues 1–3, 17 February 2007, Pages 44–49
نویسندگان
Kaustavmoni Deka, Nilotpal Barooah, Rupam Jyoti Sarma, Jubaraj B. Baruah,