کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
146326 | 456367 | 2015 | 8 صفحه PDF | دانلود رایگان |
• TiO2 nanoparticles were immobilized on the inner surface of glass capillaries.
• The catalytic system was used for ODS of DBT and discoloration of MO.
• TiO2 nanoparticles showed good crystallization with a mean size of 6.8 nm.
• 100% conversions of DBT and MO were obtained after 2.8 min and 40 s, respectively.
In this work, we have successfully immobilized TiO2 nanoparticles with small particle size and narrow size distribution on the inner surface of glass capillaries. By integrating the beneficial properties of nano-sized TiO2 particles with microreactors, the highly efficient catalytic system showed good performance in oxidation of dibenzothiophene (DBT) and photocatalytic discoloration of methyl orange (MO). The mean particle size and loading amount (Ti content: 0.21–2.81 wt.%) are both controllable via the simple manufacturing procedure. The diameter varied from 6.8 to 20.8 nm with the pH increased from 1.59 to 6.48 using ethanol as the solvent. Particles prepared by methanol showed the largest size (18.2 nm) and broadest size distribution compared with those synthesized with ethanol and isopropanol. DBT was converted completely within 2.8 min with an initial concentration of 20 ppm, and 100% discoloration of MO was obtained after 40 s. The highly efficient microreactor is easy to be integrated on a large scale, thus providing a highly promising alternative for a broad range of catalytic applications.
We have successfully immobilized TiO2 nanoparticles with small particle size (6.8 nm) and narrow size distribution on the inner surface of glass capillaries. By integrating the beneficial properties of nano-sized TiO2 particles with microreactors, the highly efficient catalytic system showed good performance in oxidation of dibenzothiophene (DBT) and photocatalytic discoloration of methyl orange (MO). DBT was converted completely within 2.8 min with an initial concentration of 20 ppm, and 100% discoloration of MO was obtained after 40 s.Figure optionsDownload as PowerPoint slide
Journal: Chemical Engineering Journal - Volume 277, 1 October 2015, Pages 48–55