کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
146450 | 456371 | 2015 | 9 صفحه PDF | دانلود رایگان |
• Mesoporous activated carbon (AC) was prepared from sodium hydroxide activation of hydrochar of palm date seed.
• The BET of AC prepared using 1:3 NaOH impregnation ratio was 1282.49 m2/g and 20.73 Å average pore width.
• The maximum MB adsorption capacities of 612.1, 464.3, and 410.0 mg/g were obtained at 30, 40, and 50 °C, respectively.
Mesoporous activated carbon (AC) was prepared via sodium hydroxide (NaOH) activation of hydrochar from the hydrothermal carbonization (HTC) of palm date seed (PDS). The textural, morphological, and chemical properties of the produced hydrochar AC were investigated. NaOH activation enhanced the porosity and surface functionality of the hydrochar. Batch equilibration methods were performed to explore the process parameters that affected the adsorption of the prepared AC on methylene blue (MB), including initial concentration, contact time, solution pH and temperature. The Freundlich isotherm model better depicted the equilibrium data compared with the Langmuir isotherm model. Temperature was found to negatively affect the adsorption capacity of the prepared AC, which exhibited 612.1, 464.3 and 410.0 mg/g maximum MB adsorption capacities at 30, 40 and 50 °C, respectively. The pseudo-second order kinetic model best described the kinetic data. HTC and NaOH activation was proven to be an effective method in preparing highly porous AC from PDS, with good potential for cationic dye removal from liquid phase.
Journal: Chemical Engineering Journal - Volume 270, 15 June 2015, Pages 187–195