کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1472233 | 990375 | 2006 | 10 صفحه PDF | دانلود رایگان |
Some S-containing compounds newly synthesised have been tested as inhibitors for the corrosion of steel in 1 M HCl solution. Weight loss measurements, potentiodynamic polarisation and impedance spectroscopy (EIS) methods are used. The inhibiting action increases with the concentration of the compounds tested. The highest efficiency 95% is obtained at 10−4 M of [(11-hydroxyundecyl)thio]acetic acid (3 and 4). We note good agreement between gravimetric and electrochemical methods (potentiodynamic polarisation and EIS). Polarisation measurements show also that 3 and 4 act as mixed inhibitors. The cathodic curves indicate that the reduction of proton at the steel surface happens with an activating mechanism. 3 adsorbs on the steel surface according to Langmuir adsorption model. Effect of temperature is also studied between 308 K and 353 K.
Journal: Corrosion Science - Volume 48, Issue 9, September 2006, Pages 2470–2479