کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
148059 456404 2014 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Loop vs. batch reactor setups in the fractionation of birch chips using switchable ionic liquids
ترجمه فارسی عنوان
تنظیم حلقه در مقابل راکتورهای دسته ای در تقسیم کردن تراشه های توس با استفاده از مایعات قابل تعویض یونی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


• Batch and loop reactors for efficient fractionation of wood.
• Partial fractionation of wood into cellulose, hemicellulose and lignin.
• Fractionation of birch chips using switchable ionic liquids.
• Effects of mass and heat transfer on wood fractionation.
• Dissolution and recovery of fractionated components.

The fractionation of lignocellulosic feedstock into its major components with high purity represents an important commercialization milestone in the transformation of lignocellulosic forest derived products into fuels and commodity chemicals. A comparison between the traditionally used batch reactor and loop reactor systems demonstrates that improved dissolution of hemicelluloses and lignin are obtained using switchable ionic liquids in a loop reactor system which facilitates decreased heat and mass transfer restrictions. The treatment of birch chips using switchable ionic liquid (SIL) based on 1,8-diazabicyclo-[5.4.0]-undec-7-ene, CO2 and diethanolamine at 120 °C for 30 h in a loop reactor resulted in 24% loss of original weight of wood corresponding to dissolution of 52 wt.% of hemicelluloses and 42 wt.% of lignin, respectively, as opposed to 20% weight loss corresponding to 43 wt.% dissolution of hemicelluloses and 38 wt.% of lignin in the batch system. The non-dissolved material obtained from both reactors was efficiently fibrillated and softened cellulose fibres. The flow of switchable ionic liquid through the loop reactor and agitation of the chips enhanced the dissolution of hemicelluloses and lignin. The dissolved fractions recovered from spent SIL after treatment contained both hemicelluloses and lignin.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 238, 15 February 2014, Pages 242–248
نویسندگان
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