کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
148263 456408 2013 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Catalytic degradation of a plasticizer, di-ethylhexyl phthalate, using Nx–TiO2−x nanoparticles synthesized via co-precipitation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Catalytic degradation of a plasticizer, di-ethylhexyl phthalate, using Nx–TiO2−x nanoparticles synthesized via co-precipitation
چکیده انگلیسی


• Nx–TiO2−x nanoparticles were successfully synthesized via co-precipitation procedure.
• Nx–TiO2−x nanoparticles were used to remove wastewater pollutant containing plasticizer.
• The catalytic activity was tested by coupling with ozone and visible light.

There is an increasing concern in the decontamination of wastewater. Most of the advanced oxidation procedures described so far are based on the use of different oxidation reactions including photocatalysis and ozonation. Doped titanium dioxide nanoparticles are photoactive under visible light illumination, being therefore possible to harvest solar energy for water decontamination. In this study, anatase Nx–TiO2−x nanoparticles were successfully synthesized by a simple co-precipitation procedure based on the oxidation of titanous (III) chloride in the presence of ammonia. The transmission electron microscope images of Nx–TiO2−x show nanoparticles with an average diameter size of ∼13 nm. The presence of nitrogen (N1s) was verified using XPS analysis. The characteristic peak at 400 eV indicates the formation of O–Ti–N bonds. The Nx–TiO2−x nanoparticles were found to be useful for the removal of a wastewater pollutant use as plasticizer (di-ethylhexyl phthalate) by a combined process of heterogeneous photocatalysis under visible illumination coupled with ozonation. The photoactivity of the Nx–TiO2−x nanopowder is enhanced compared to commercial TiO2 P25 nanoparticles due to the generation of electron/hole pairs under visible irradiation together with a larger electrocatalytic activity towards oxygen reduction.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 231, September 2013, Pages 182–189
نویسندگان
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