کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
149672 456435 2012 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solid combustion wave with two successive reactions to produce phosphor powders
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Solid combustion wave with two successive reactions to produce phosphor powders
چکیده انگلیسی

A solid combustion approach consisting of two successive reactions is developed for producing metal oxide (Y3Al5O12:Ce3+), silicate (Zn2SiO4:Mn2+), and borate (YBO3:Eu3+) phosphor powders. The typical precursors for the phosphor synthesis were the corresponding metal oxides. The entire combustion process was driven by a KClO3 + CO(NH2)2 exothermic mixture preliminarily admixed with precursor oxide powders. Small amounts of NH4F were also used to accelerate the phosphor formation and crystallization processes. The optimal synthesis temperatures estimated from the temperature distributions were between 700 and 1200 °C, and the combustion velocity varied from 0.04 to 0.5 cm/s. From the synthesis, well-dispersed phosphor microparticles with a controlled morphology were obtained. The roles of the KClO3 + CO(NH2)2 exothermic reaction and the NH4F additive were examined in the context of the reaction mechanism and the phosphor powder characteristics. The obtained combustion-synthesized phosphors were of high quality and single phase having high luminescence characteristics.

Figure optionsDownload as PowerPoint slideHighlights
► Two-successive reaction pathway is developed for rapid synthesizing phosphor powders.
► Temperature distributions were analyzed and a combustion mechanism is proposed.
► Single phase phosphor microparticles at low temperature (700–1200 °C) are prepared.
► Phosphors show controlled morphology, good dispersion and high luminescence efficiency.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volumes 198–199, 1 August 2012, Pages 449–456
نویسندگان
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