کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
149922 456440 2012 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Pure and mixed gas CH4 and n-C4H10 permeation in PDMS-fumed silica nanocomposite membranes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Pure and mixed gas CH4 and n-C4H10 permeation in PDMS-fumed silica nanocomposite membranes
چکیده انگلیسی

Nanocomposite membranes of polydimethylsiloxane (PDMS) with different amounts of fumed silica were synthesized over a porous support of polyacrylonitrile. The prepared membranes were characterized using atomic force microscopy and thermal gravimetric analysis. AFM results indicated the nanoscale dispersion of silica particles in polymer matrix. TGA results indicated that increasing the silica content enhances the thermal stability of membranes. Permeation of methane and n-butane single gases at different upstream pressures and also permeation of a gas mixture containing 3 mol% of n-butane in methane were studied and discussed. The results showed that the nanocomposite membrane containing 11 wt% of fumed silica exhibited 38% increment in permeability of n-butane and simultaneously 30% increase in selectivity of n-butane over methane. The unusual property enhancement that contradicts to that of conventional filled polymer systems has been discussed based on density of membranes and free volume concept.


► Addition of 5.5 wt% FS decreased the permeability but 11 and 16.5 wt% of FS increased it.
► Single gas selectivity of nanocomposite membranes was lower than that in neat PDMS.
► Mixed gas selectivity of nanocomposite membranes were higher than that for neat PDMS.
► Addition of 11 wt% of FS simultaneously increased the permeability and selectivity.
► Free volume mechanism was the main effective mechanism in gas transport.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 191, 15 May 2012, Pages 369–377
نویسندگان
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