کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1505209 | 993755 | 2011 | 4 صفحه PDF | دانلود رایگان |
An in situ high-pressure X-ray diffraction study has been carried out at room temperature up to 9.23 GPa on a crystal of Ca2Sb2O7 having a weberite-2O structure synthesized by solid-state reaction. A 2nd-order Birch–Murnaghan Equation of State (EoS) was used to refine the pressure–volume data. The refinement of the unit-cell volume and of the isothermal bulk modulus at room pressure leads to: V0 = 555.8 (1), KT0 = 154.6 (9) GPa. Unit-cell parameters decrease gradually as a function of pressure with a bulk modulus anisotropy scheme Ka0 > Kb0 > Kc0, with c being the softest direction. The compressional behavior of Ca2Sb2O7 is compared with that shown by ingersonite, Ca3MnSb4O14, a mineral showing a weberite-3T structure.
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Journal: Solid State Sciences - Volume 13, Issue 5, May 2011, Pages 1092–1095