کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
150817 456457 2011 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of ozone treatment on properties of expanded graphite
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Effect of ozone treatment on properties of expanded graphite
چکیده انگلیسی

In this work, ozone modification of expanded graphite (EG) was carried out by streaming ozone through a bed of EG. The results of the reaction were evaluated using structural (Brunauer, Emmet and Teller – BET) and surface chemical composition (X-ray photoelectron spectroscopy – XPS) analysis. Electrochemical activity of ozone-treated EG was studied in the model process of phenol electrooxidation in alkaline solutions using cyclic voltammetry (CV). It can be pointed out that the results of EG modification strongly depend on the temperature of the ozone treatment. Indeed, the process carried out at room temperature yielded CO containing functional groups on the surface, whereas at higher temperatures C–O species were predominantly formed instead, with a simultaneous considerable increase in the specific surface area. Electrochemical studies revealed that phenol electrooxidation was promoted by the EG ozone-modified at elevated temperatures.


► Properties of ozonated expanded graphite depend on temperature of ozone treatment.
► Ozonation of expanded graphite modifies its structural properties and chemical composition of its surface.
► Phenol electrooxidation is promoted by expanded graphite ozone-modified at elevated temperatures.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 172, Issues 2–3, 15 August 2011, Pages 1096–1102
نویسندگان
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