کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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152226 | 456491 | 2009 | 8 صفحه PDF | دانلود رایگان |
The amino acid l-cysteine (l-Cys) was intercalated into a MgAl layered double hydroxide (LDH), and its oxidation reaction by hexacyanoferrate (III) (Fe(CN)63−) in the confined region between sheets of LDH has been studied in detail. Based on the measurement results of XRD, Raman and FT-IR, it was found that the interlayer l-Cys was oxidized to cystine by Fe(CN)63−. Furthermore, the kinetics of this reaction was investigated in batch mode. The influences of initial Fe(CN)63−concentration, l-Cys-LDH quantity and reaction temperature on the interlayer oxidation reaction have been studied, respectively. The reaction follows a diffusion-controlled mechanism represented by Crank-Ginstling and Brounshtein kinetic model with the apparent activation energy of 29.93 kJ/mol. Therefore, this layered material may have prospective application as a novel “molecular reactor” for confined chemical reactions.
Journal: Chemical Engineering Journal - Volume 153, Issues 1–3, 1 November 2009, Pages 175–182