Mid-infrared luminescence and energy transfer of Tm3+/Yb3+ doped fluorophosphate glass

Tm3+/Yb3+-codoped fluorophosphate glass is prepared by conventional melt-quenching method and the thermal stability of the glass is analyzed. The Judd–Ofelt parameters, radiation emission rates, radiative lifetime and branching ratios of prepared samples are calculated based on the absorption spectra. Upon excitation of a conventional 980 nm laser diode, 1.8 μm emission is obtained from Yb3+/Tm3+ codoped fluorophosphate. Additionally, the energy transfer between Yb3+ and Tm3+ ions are quantitatively analyzed. Hence, this Yb3+/Tm3+ codoped fluorophosphate glass possessing high energy transfer efficiency and excellent thermal stability is a good candidate for efficient 1.8 μm laser.

► Tm3+/Yb3+ doped fluorophosphate glass is prepared.
► The thermal stability and optical properties of the glass is analyzed.
► 1.8 μm emission is obtained from Yb3+/Tm3+ codoped fluorophosphates glass.
► Present glass possesses high energy transfer coefficient and efficiency.
► Tm3+/Yb3+ doped fluorophosphate glass is a candidate for efficient 1.8 μm laser.