کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1564877 | 999777 | 2015 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Self-propagating high-temperature synthesis of Ce-bearing zirconolite-rich minerals using Ca(NO3)2 as the oxidant
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی هسته ای و مهندسی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Self-propagating high-temperature synthesis of Ce-bearing zirconolite-rich minerals using Ca(NO3)2 as the oxidant Self-propagating high-temperature synthesis of Ce-bearing zirconolite-rich minerals using Ca(NO3)2 as the oxidant](/preview/png/1564877.png)
چکیده انگلیسی
Synroc is recognized as the second generation waste form for the immobilization of high-level radioactive waste (HLW). Zirconolite-rich (CaZrTi2O7) Synroc minerals were attempted by self-propagating high-temperature synthesis (SHS) using Fe2O3, CrO3, Ca(NO3)2 as the oxidants and Ti as the reductant. All designed reactions were ignited and sustained using Ca(NO3)2 as the oxidant, and zirconolite-rich ceramic matrices were successfully prepared with pyrochlore (Ca2Ti2O6), perovskite (CaTiO3) and rutile (TiO2) as the minor phases. The sample CN-4, which was designed using Ca(NO3)2 as the oxidant with TiO2/Ti ratio of 7:9, was readily solidified with density of 4.62Â g/cm3 and Vickers hardness of 1052Â HV. CeO2 was successfully stabilized by the CN-4 sample with resultant phase constituent of 2M-CaZrTi2O7 and CaTiO3.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Nuclear Materials - Volume 467, Part 1, December 2015, Pages 214-223
Journal: Journal of Nuclear Materials - Volume 467, Part 1, December 2015, Pages 214-223
نویسندگان
Kuibao Zhang, Guanjun Wen, Dan Yin, Haibin Zhang,