کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1605080 1516208 2016 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
ZnO/TiO2 nanohexagon arrays heterojunction photoanode for enhancing power conversion efficiency in dye-sensitized solar cells
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
ZnO/TiO2 nanohexagon arrays heterojunction photoanode for enhancing power conversion efficiency in dye-sensitized solar cells
چکیده انگلیسی


• ZnO/TiO2 nanohexagon heterojunction was introduced by immersing method.
• Higher surface area for dye uploading and low recombination rate.
• ZnO/TiO2 nanohexagon heterojunction based photoanode has PCE of 6.85%.

TiO2 nanohexagon arrays (TNHAs) were grown by anodization of Ti foil in an electrolyte containing NH4F, and then the TNHAs were transferred onto FTO glass by using a drop of sol containing Ti(OBu)4 for fabricating a front-side illumination cell. In order to improve the power conversion efficiency (PCE) of the as-fabricated dye-sensitized solar cells (DSSCs), ZnO was introduced into the TNHAs by a facile immersing method. The as-obtained ZnO/TiO2 nanohexagon heterojunction was used as the photoanode for DSSCs, which is expected to have a low recombination rate and high absorption of light. Results indicated that the DSSCs based on the ZnO/TNHAs exhibit an enhanced current density and high PCE of 6.85% under 100 mW cm−2 illumination. Furthermore, electrochemical impedance spectroscopy showed that the ZnO/TNHAs heterojunction-based DSSCs have optimized electron properties, including longer electron lifetime, lower resistance to electron transport, and smaller probability for electron recombination as compared to the DSSCs fabricated from pure TNHAs as photoanode.

Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 685, 15 November 2016, Pages 610–618
نویسندگان
, , , , , ,