کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1607258 | 1516234 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Low-temperature direct synthesis of layered m-LiMnO2 for lithium-ion battery applications
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Layered monoclinic LiMnO2 is a potential low-cost alternative to LiCoO2 cathode for lithium-ion batteries. However, its application is limited partly because it cannot be synthesized easily. In this work, we successfully synthesized phase-pure layered LiMnO2 in a one-step low-temperature process using electrolytic manganese dioxide (EMD) as the manganese precursor at 450 °C in Ar atmosphere by a carbothermal reduction method. The initial carbon to manganese ratio has to be optimized to remove impurities. The particle size of the material is between 40 and 60 nm. The synthesized sample shows an initial reversible capacity of about 180 mAh gâ1. The synthesis method is further applied to make boron-doped samples, which significantly enhanced the stability of the material, especially at high temperature. The boron-doped samples maintain a capacity of 150 mAh gâ1 for 100 cycles and give a capacity of about 100 mAh gâ1 at a current of 1000 mA gâ1 (equivalent to 10C rate). The ability to directly synthesize the material at low temperature is crucial because it allows further improvement of material performances through methods such as surface coating and the use of electrolyte additives to reduce surface reaction and Mn-dissolution.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 659, 25 February 2016, Pages 248-254
Journal: Journal of Alloys and Compounds - Volume 659, 25 February 2016, Pages 248-254
نویسندگان
Hui Zhou, Yingshun Li, Jiaolong Zhang, Wenpei Kang, Denis Y.W. Yu,