کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1607359 | 1516236 | 2016 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Properties and electrochemical performance of Sr0.8La0.2TiO3âδ-Ce0.8Gd0.2O2âδ composite anodes for intermediate temperature solid oxide fuel cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
A series of Sr0.8La0.2TiO3âδ (SLT)-Ce0.8Gd0.2O2âδ (GDC) composite anodes with various volume ratios of SLT and GDC has been synthesized using a sucrose modified combustion technique. The percolation thresholds of Sr0.8La0.2TiO3âδ and Ce0.8Gd0.2O2âδ in the composite calculated based on the Kusy's percolation theory were 75.6 vol.% and 36.1 vol.%, respectively. While the rate of carbon deposition increased with an increase in the Ce0.8Gd0.2O2âδ content, the total electrical conductivity decreased in humidified H2 as well as in CH4. Based on the electrochemical performance measured using AC-impedance spectroscopy, the optimal anode composition was 65 vol.% Sr0.8La0.2TiO3âδ-35 vol.% Ce0.8Gd0.2O2âδ. This composite has polarization resistances of 2.80 Ω cm2 and 4.60 Ω cm2 in H2 and CH4, respectively, measured at 800 °C. Diffusion or concentration polarization was the rate determining steps for the fuel oxidation process in the Sr0.8La0.2TiO3âδ-Ce0.8Gd0.2O2âδ composite anode.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 657, 5 February 2016, Pages 537-545
Journal: Journal of Alloys and Compounds - Volume 657, 5 February 2016, Pages 537-545
نویسندگان
Manasa K. Rath, Ki-Tae Lee,