کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1609162 | 1516258 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Improving the electrochemical kinetics of lithium manganese phosphate via co-substitution with iron and cobalt
ترجمه فارسی عنوان
بهبود سینتیک الکتروشیمیایی فسفات منگنز لیتیوم از طریق جایگزینی با آهن و کبالت
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کلمات کلیدی
فسفات منگنز لیتیم، واکنش حالت جامد، جایگزینی، مواد کاتدی،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
چکیده انگلیسی
High Mn content multicomponent olivine phosphate LiMn0.9Fe0.1âxCoxPO4/C (x = 0, 0.05 and 0.1) are synthesized by two-step solid-state method and characterized by X-ray powder diffraction, FTIR spectra, XPS, electron microscopy and electrochemical measurements. Upon substitution, the cell volume decrease as a result of the smaller ionic radii of Fe2+ and Co2+ compared to Mn2+. Structural analysis demonstrates that Fe and/or Co substitution decrease the Mn-O and P-O bond length and increase the Li-O bond length, leading to enhanced physical stability and expanded Li diffusion channels. The Fe2+ and/or Co2+ substituted LiMnPO4 is found to have improved kinetics, lithium storage performance, and electronic conductivity during electrochemical reaction. In particular, LiMn0.9Fe0.05Co0.05PO4/C delivers a capacity of 145 mA h gâ1 at a current of 0.05 C and exhibits enhanced capacity retention compared to that of unmodified LiMnPO4/C. The enhanced electrochemical performance of co-substituted LiMnPO4 is attributed to the enhanced physical stability, the favorable delithiation/lithiation induced by previous redox reaction of Fe2+/Fe3+and Co2+/Co3+ and the improved electric/ionic transport properties.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 635, 25 June 2015, Pages 180-187
Journal: Journal of Alloys and Compounds - Volume 635, 25 June 2015, Pages 180-187
نویسندگان
Wei Xiang, Yanjun Zhong, Yan Tang, Huihui Shen, Enhui Wang, Heng Liu, Benhe Zhong, Xiaodong Guo,