کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1612314 | 1516306 | 2014 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The equilibrium between metallic titanium and titanium ions in LiCl-KCl melts
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
The equilibrium between metallic titanium and titanium ions (Ti2+, Ti3+) dissolved in LiCl-KCl melts and the influence of the electrolyte composition on the equilibrium were investigated. The accurate concentrations of titanium ions had been obtained based on a reliable approach for taking samples. Furthermore, accurate values of the equilibrium constants were calculated by the best-fitting method under the consideration of the TiOCl dissolution. The influence of the electrolyte composition on the equilibrium was evaluated by determining the equilibrium constant Kc between titanium metal and titanium ions in LiCl-KCl melts with different concentration of LiCl. It was shown that LiCl could affect the equilibrium and the Kc values decreased with the increase of concentration of LiCl.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 587, 25 February 2014, Pages 349-353
Journal: Journal of Alloys and Compounds - Volume 587, 25 February 2014, Pages 349-353
نویسندگان
Xiaobo Zhu, Qiuyu Wang, Jianxun Song, Jungang Hou, Shuqiang Jiao, Hongmin Zhu,