کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1613568 | 1516319 | 2013 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, characterization and understanding of the mechanisms of electroplating of nanocrystalline-amorphous nickel-tungsten alloys using in situ electrochemical impedance spectroscopy
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this study, a series of Nickel (Ni)-Tungsten (W) alloys were electrodeposited onto copper (Cu) substrates using electroplating baths and tri-sodium citrate (Na3C6H5O7) as the complex agent. The electro co-deposition of Ni-W alloys was carried out by varying several important experimental parameters: the tungstate ion [WO4]2- concentration, the bath temperature and the speed of stirring. Potentio-dynamic polarization and in-situ electrochemical impedance spectroscopy (EIS) techniques were used as electroplating methods to study the processes. The phases present in the films were identified using powder X-ray diffraction (XRD) and electron diffraction (ED). The films were examined using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) and their elemental compositions determined using X-ray energy dispersive spectrometry (XEDS). The electrodeposited films were found to be a mixture of amorphous and nanocrystalline Ni-W. This study has allowed us to reach a better understanding of the complex mechanisms and effective parameters of co-deposition of Ni and W using citrate ions complex baths.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 574, 15 October 2013, Pages 196-205
Journal: Journal of Alloys and Compounds - Volume 574, 15 October 2013, Pages 196-205
نویسندگان
Majid Ahmadi, Maxime J-F. Guinel,