کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1614946 | 1516342 | 2013 | 4 صفحه PDF | دانلود رایگان |
Fluorine (F) doping in (In1−xFex)2O3 was achieved by the process of a low temperature reaction with polyvinylidene fluoride (PVDF). Ferromagnetism with a Curie temperature as high as 675 K was obtained in the F-doped (In1−xFex)2O3. It is found that F doping leads to reduction of Fe valence state from Fe3+ to Fe2+. The saturated magnetic moment (Ms) shows a maximum value when the ratio of Fe2+/Fe3+ is 50%, indicating that the mixed-valence Fe2+–Fe3+ pairs play an important role in inducing the ferromagnetism. Interestingly, it is further found that the ferromagnetism in the F-doped (In1−xFex)2O3 still exists even after high temperature annealing in air.
► Fluorine (F) doping in (In1−xFex)2O3 was achieved by the process of a low temperature reaction with polyvinylidene fluoride.
► Ferromagnetism was obtained in the F-doped (In1−xFex)2O3.
► The Curie temperature of ferromagnetism is as high as 675 K.
► The ferromagnetism originates from the mixed-valence Fe2+–Fe3+ pairs.
► The ferromagnetism in the F-doped (In1−xFex)2O3 still exists even after high temperature annealing in air.
Journal: Journal of Alloys and Compounds - Volume 551, 25 February 2013, Pages 40–43