LiFe0.8Mn0.2PO4/C cathode material with high energy density for lithium-ion batteries

LiFe0.8Mn0.2PO4/C composites are synthesized via solid state reaction promoted by wet ball milling. Synthesis conditions are optimized to obtain desirable crystallization, morphology, particle size and specific surface area. Our experiments show that the LiFe0.8Mn0.2PO4/C sample sintered at 600 °C exhibits the best performance with initial discharge capacities of 160 mAh g−1 at 0.1 C, 133 mAh g−1 at 5 C and 122 mAh g−1 at 10 C. At 5 C, the cathode exhibits an excellent cyclability over 100 cycles, and the average specific energy density is as high as 414 Wh kg−1. We attribute the superior performance to well crystallization, uniform morphology, small particle size and high specific surface area. Our results indicate that partial substitution of Mn ions for Fe ions can significantly improve rate capability and energy density in LiFePO4. LiFe0.8Mn0.2PO4 should be identified as highly promising cathode material with high energy density.

► Mn substitution for Fe to achieve LiFe0.8Mn0.2PO4 cathode material.
► Optimization of synthesis condition for LiFe0.8Mn0.2PO4/C composite.
► Initial discharge capacities of 160 and 122 mAh g−1 at 0.1 and 10 C, respectively.
► Significantly high energy density in Mn-doped LiFePO4.