کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1617801 | 1005695 | 2011 | 6 صفحه PDF | دانلود رایگان |

Mg2Si:Gax and Mg2Si0.6Ge0.4:Gax (x = 0.4% and 0.8%) solid solutions have been synthesized by direct melting in tantalum crucibles and hot pressing. The effect of Ga doping on the thermoelectric properties has also been investigated by measurements of thermopower, electrical resistivity, Hall coefficient and thermal conductivity in temperature range from 300 to 850 K. All samples exhibit a p-type conductivity evidenced by positive sign of both thermopower and Hall coefficient in the investigated temperatures. The maximum value of the dimensionless figure of merit ZT was reached for the Mg2Si0.6Ge0.4:Ga(0.8%) compound at 625 K (ZT ∼ 0.36). The p-type character of thermoelectric behaviours of Ga-doped Mg2Si and Mg2Si0.6Ge0.4 compounds well corroborates with the results of electronic structure calculations performed by the Korringa–Kohn–Rostoker method and the coherent potential approximation (KKR-CPA), since Ga diluted in Mg2Si and Mg2Si0.6Ge0.4 (on Si/Ge site) behaves as hole donor due to the Fermi level shifted to the valence band edge. The onset of large peak of DOS from Ga impurity at the valence band edge, well corroborates with high Seebeck coefficient measured in Ga-doped samples.
► Mg2Si1−xGex alloys are the promising thermoelectric materials working in the middle temperature range (500–850 K).
► These materials can be used for heat recovery and energy conversion applications.
► Ga doping affects the thermoelectric properties and materials are p-type.
Journal: Journal of Alloys and Compounds - Volume 509, Issue 23, 9 June 2011, Pages 6503–6508