کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1618936 1005714 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation of a Gd0.1Ce0.9O2 − δ interlayer for intermediate-temperature solid oxide fuel cells by spray coating
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Preparation of a Gd0.1Ce0.9O2 − δ interlayer for intermediate-temperature solid oxide fuel cells by spray coating
چکیده انگلیسی

Spray coating is widely used in industrial applications for the preparation of large, uniform thin films on various substrates due to its simplicity and cost-efficiency. To prevent reactions between a yttria-stabilised zirconia (YSZ) electrolyte and a La0.6Sr0.4Co0.2Fe0.8O3 − δ (LSCF) cathode, a Gd0.1Ce0.9O2 − δ (CGO) interlayer with a thickness of 2–3 μm is prepared on a YSZ electrolyte by spray coating. The results indicate that the properties of the CGO interlayer depend on its preparation conditions, including the powder pre-sintering temperature, the concentration of the dispersant and the sintering temperature. A densely packed CGO interlayer is obtained from a well-dispersed suspension of CGO powder pre-sintered at 750 °C with 6 wt.% PVP as a dispersant. After sintering at 1250 °C and 1300 °C, the CGO interlayer achieves an area special resistance (ASR) of 0.1 Ω cm2 at 800 °C and 0.4 Ω cm2 at 700 °C. Moreover, LSCF cells with a CGO interlayer obtain an average maximum power density greater than 600 mW cm−2 at 750 °C. Obvious diffusion of Sr is not observed in the cells, indicating that the CGO interlayer prepared by spray coating effectively blocks Sr diffusion.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 505, Issue 1, 27 August 2010, Pages 118–124
نویسندگان
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