Preparation and characterization of CuInSe2 thin films by chemical bath deposition technique

Copper indium diselenide (CIS) thin films have been deposited using a precursor solution containing copper sulphate, indium trichoride, hydrazine hydrate and sodium selenosulphate in an aqueous alkaline medium at room temperature. The as grown brown colored films were found to be well adherent to glass substrates. The films were characterized by X-ray diffraction, scanning electron microscopy, atomic absorption spectroscopy, optical absorption, electrical resistivity, and thermo electric measurement techniques. The analysis of optical absorption data shows band-gap energy (Eg) to be 1.1 eV. The electrical resistivity of the thin film was found to be of the order of 102 (Ω cm). Thermoelectric power measurement shows n-type conduction.