کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1620980 | 1005741 | 2010 | 7 صفحه PDF | دانلود رایگان |
In this paper, the microstructural evolution of IMCs in Sn–3.5Ag–X (X = 0, 0.75Ni, 1.0Zn, 1.5In)/Cu solder joints and their growth mechanisms during liquid aging were investigated by microstructural observations and phase analysis. The results show that two-phase (Ni3Sn4 and Cu6Sn) IMC layers formed in Sn–3.5Ag–0.75Ni/Cu solder joints during their initial liquid aging stage (in the first 8 min). While after a long period of liquid aging, due to the phase transformation of the IMC layer (from Ni3Sn4 and Cu6Sn phases to a (Cu, Ni)6Sn5 phase), the rate of growth of the IMC layer in Sn–3.5Ag–0.75Ni/Cu solder joints decreased. The two Cu6Sn5 and Cu5Zn8 phases formed in Sn–3.5Ag–1.0Zn/Cu solder joints during the initial liquid aging stage and the rate of growth of the IMC layers is close to that of the IMC layer in Sn–3.5Ag/Cu solder joints. However, the phase transformation of the two phases into a Cu–Zn–Sn phase speeded up the growth of the IMC layer. The addition of In to Sn–3.5Ag solder alloy resulted in Cu6(Snx,In1−x)5 phase which speeded up the growth of the IMC layer in Sn–3.5Ag–1.5In/Cu solder joint.
Journal: Journal of Alloys and Compounds - Volume 489, Issue 2, 21 January 2010, Pages 631–637