کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1622410 1516394 2009 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of similar elements on improving glass-forming ability of La–Ce-based alloys
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Effect of similar elements on improving glass-forming ability of La–Ce-based alloys
چکیده انگلیسی

To date the effect of unlike component elements on glass-forming ability (GFA) of alloys have been studied extensively, and it is generally recognized that the main consisting elements of the alloys with high GFA usually have large difference in atomic size and atomic interaction (large negative heat of mixing) among them. In our recent work, a series of rare earth metal-based alloy compositions with superior GFA were found through the approach of coexistence of similar constituent elements. The quinary (La0.5Ce0.5)65Al10(Co0.6Cu0.4)25 bulk metallic glass (BMG) in a rod form with a diameter up to 32 mm was synthesized by tilt-pour casting, for which the glass-forming ability is significantly higher than that for ternary Ln–Al–TM alloys (Ln = La or Ce; TM = Co or Cu) with critical diameters for glass-formation of several millimeters. We suggest that the strong frustration of crystallization by utilizing the coexistence of La–Ce and Co–Cu to complicate competing crystalline phases is helpful to construct BMG component with superior GFA. The results of our present work indicate that similar elements (elements with similar atomic size and chemical properties) have significant effect on GFA of alloys.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 483, Issues 1–2, 26 August 2009, Pages 60–63
نویسندگان
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