کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1623652 | 1516409 | 2009 | 6 صفحه PDF | دانلود رایگان |

Vanadium carbide (V8C7) nanopowders can be synthesized by thermal processing the precursor of ammonium vanadate (NH4VO3), glucose (C6H12O6) and urea. The products were characterized by X-ray diffractometry (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and Brunauer–Emmett–Teller (BET) techniques. The results show that the single-phase V8C7 powders can be obtained at 1000 °C for 1 h. The powders exhibit the morphology of square or spheroidal and consist of multiple particles ∼200 nm in size. The surface of the specimen mainly consists of V, C and O three species elements. The V 2p peaks with the binding energy of 517.4, 516.2 and 513.6 eV are assigned to the V 2p3/2 species of V2O5, VO2 and V8C7, respectively. The XPS spectrum of O 1s energy region for vanadium carbide contains two peaks corresponding to OH− (532.2 eV) and V5+ (530.4 eV). The BET specific surface area, the average pore size and the measured are 17.60 m2/g, 2.44 nm and 0.06 cm3/g, respectively.
Journal: Journal of Alloys and Compounds - Volume 468, Issues 1–2, 22 January 2009, Pages 58–63