کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1625159 | 1516426 | 2008 | 8 صفحه PDF | دانلود رایگان |

In this study we give evidence for the strong dependence of the compositional and magnetic properties on the synthesis conditions of polycrystalline Co2(Cr1−xFex)Al Heusler alloys (0 ≤ x ≤ 1) by comparing the properties of as-grown and annealed compounds. Strong chemical inhomogeneities are found at the micrometric level depending on the compound and the synthesis method. Moreover, we find that the Co content is homogeneous at the micrometric level in all the studied samples in sharp contrast with significant inhomogeneous distribution of (Fe/Cr) and Al at the micrometric level, especially for Cr-rich compounds (x ≤ 0.4). We have found that the magnetic properties (the Curie temperature and the saturation magnetization) are strongly depressed in the annealed compounds with respect to the corresponding as-grown compounds. For the as-grown compounds the saturation magnetization is close to the theoretically predicted one for x ≥ 0.7 whereas it is lower than the theoretically predicted one for x ≤ 0.4, which correlates with the observed chemical inhomogeneity.
Journal: Journal of Alloys and Compounds - Volume 450, Issues 1–2, 14 February 2008, Pages 31–38