کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1627544 | 1516456 | 2006 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hydrogen spillover and structural defects in a PdO/zirconia nanophase synthesized through a surfactant-templated route
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Hydrogen spillover and structural defects in a PdO/zirconia nanophase synthesized through a surfactant-templated route Hydrogen spillover and structural defects in a PdO/zirconia nanophase synthesized through a surfactant-templated route](/preview/png/1627544.png)
چکیده انگلیسی
Nanosized zirconia with structural defects was synthesized by using surfactant-templated method. The average crystallite size, phase composition, cationic defect concentration and structural microstrain in the monoclinic phase of zirconia annealed at 800 °C were quantitatively determined by the Rietveld refinement. An unusual behaviour of hydrogen reversibly storing into/releasing from the PdO/ZrO2 nanophases was observed, which related to formation/decomposition of a hydride phase β-PdH0.76 and to hydrogen storage in the cationic defects of zirconia nanophases by means of hydrogen spillover from Pd metals to zirconia support.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 417, Issues 1–2, 29 June 2006, Pages 220–223
Journal: Journal of Alloys and Compounds - Volume 417, Issues 1–2, 29 June 2006, Pages 220–223
نویسندگان
L.F. Chen, J.A. Wang, M.A. Valenzuela, X. Bokhimi, D.R. Acosta, O. Novaro,