کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1643763 | 1517255 | 2014 | 4 صفحه PDF | دانلود رایگان |
• A facile in-situ method to prepare nanosulfur@polyaniline/graphene composite.
• Aniline monomer is oxidatively polymerized by graphene oxide.
• PANI grows on graphene sheet and sulfur nanoparticles embeds in PANI layer.
• The sandwich-structured composite shows enhanced electrochemical property.
• High initial and reversible capacities as cathode material for Li–S battery.
A sandwich-structured nanosulfur@polyaniline/graphene (nanoS@PANI/G) composite was synthesized through a facile method: polyaniline is polymerized in-situ on graphene sheets and sulfur nanoparticles are deposited into polyaniline layer simultaneously. Such a hierarchical framework combines multiple advantageous features, including a continuous electrically conducting polyaniline@graphene network binding with sulfur nanoparticles, high flexibility accommodating volume expansion and porous space for adsorbing the polysulfides. The resulting composite delivers a high initial capacity of 1625 mA h g−1, remaining a reversible capacity of ~600 mA h g−1 after 100 cycles, making it a promising cathode material for rechargeable lithium batteries with high energy density.
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Journal: Materials Letters - Volume 133, 15 October 2014, Pages 193–196