کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1652442 | 1517340 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Low potential electrosyntheses of high quality freestanding polyazulene films
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فناوری نانو (نانو تکنولوژی)
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چکیده انگلیسی
High quality freestanding polyazulene (PAz) films were synthesized electrochemically by direct anodic oxidation of azulene (Az) in pure boron trifluoride diethyl etherate (BFEE). The oxidation potential of Az in this medium was measured to be only 0.75 V vs. SCE. PAz films obtained from BFEE showed good electrochemical behavior with conductivity of 2.2 S cm− 1, which indicated that BFEE was a good medium for the electrosyntheses of PAz films. Structural studies implied that the Az units remained intact in the isolated 1,3-polyazulene. As-formed PAz films were insoluble in common organic solvents. To the best of our knowledge, this is the first report on the electrosyntheses of freestanding PAz films in BFEE.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 61, Issues 14–15, June 2007, Pages 3079–3082
Journal: Materials Letters - Volume 61, Issues 14–15, June 2007, Pages 3079–3082
نویسندگان
Guangming Nie, Tao Cai, Shusheng Zhang, Jian Hou, Jingkun Xu, Xuejun Han,