کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
167255 | 457849 | 2012 | 7 صفحه PDF | دانلود رایگان |
Experimental mole fraction profiles of chemical species (stable, radical and intermediates) have been measured in three CH3COOH/O2/Ar flat premixed flames burning at low pressure (50 mbar) and with equivalence ratios equal to 0.77, 0.9 and 1.05, respectively. The experimental setup used to determine the structure of one-dimensional laminar premixed flames consists of a molecular beam mass spectrometer system (MBMS) combined with electron impact ionisation (EI). Experimental results have highlighted an important role played by ketene (CH2CO) as an intermediate during the combustion of acetic acid. In order to simulate the experimental results, a sub-mechanism concerning the combustion of CH3COOH and CH2CO has been built and added to a global mechanism recently proposed. This ensures a reasonably good modelling for the structures of acetic acid flames.
Journal: Combustion and Flame - Volume 159, Issue 2, February 2012, Pages 493–499