کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1681648 1518748 2010 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Co-60 gamma radiation assisted diffusion of iodine in polypropylene
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سطوح، پوشش‌ها و فیلم‌ها
پیش نمایش صفحه اول مقاله
Co-60 gamma radiation assisted diffusion of iodine in polypropylene
چکیده انگلیسی
Thin films of polypropylene having dimensions 50 mm × 15 mm × 350 μm were immersed in 1 N iodine solution and then irradiated with Co-60 gamma radiation for the periods of 48, 96 and 144 h at the doses varying from 14.4 to 43.2 kGy. The films were also kept immersed in iodine solution for similar periods but without irradiation. Furthermore, the films were also directly-irradiated with Co-60 gamma radiation for similar periods and doses. The radiation-iodinated, plain-iodinated and directly-irradiated samples were characterized by using various techniques such as weight gain EDS, SEM, FTIR, UV-visible spectroscopy, contact angle and XRD. Weight gain, EDS and SEM collectively reveal that gamma irradiation enhances iodine intake in polypropylene. FTIR, EDS and contact angle measurements indicate that presence of iodine during irradiation resists radiation induced carbonylation of polypropylene. FTIR also shows presence of HOI (Hypoiodous acid) species instead of expected C-I bonds. UV-visible analysis unambiguously shows that presence of iodine enhances radiation induced band gap reduction process of polypropylene. XRD indicates that iodine decreases the crystallinity of polypropylene.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms - Volume 268, Issues 17–18, September 2010, Pages 2750-2757
نویسندگان
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