کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1694555 1519073 2015 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Characterization of urea-modified Palabora vermiculite
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات ژئوشیمی و پترولوژی
پیش نمایش صفحه اول مقاله
Characterization of urea-modified Palabora vermiculite
چکیده انگلیسی


• Co-intercalation urea reduces the expansion onset temperature of Palabora “vermiculite”.
• The expanded “vermiculite” exhibits spring-like behavior but there is some hysteresis.
• Vermiculite exfoliation is reversible.

Replacing the exchangeable interlayer ions in Palabora vermiculite with magnesium, aluminum or iron (III) ions does not affect the exfoliation onset temperature (456 ± 11 °C). However, co-intercalation of minor amounts of urea lowers the exfoliation onset temperature to 209 ± 35 °C. This significant decrease is attributed to the low thermal stability of urea which releases ammonia and water as blowing agents. Thermo-mechanical analysis indicates that the expanded vermiculite exhibits spring-like properties. Part of the original expansion is recovered when the applied force is removed. The observed hysteresis is attributed to the progressive flattening of warped/buckled sheets that make up the expanded worm-like structure. Provided the expanded flake has not been heated beyond 450 °C, it can be reconstituted by applying a sufficiently high compressive force followed by equilibration with distilled water. Such flakes show the conventional exfoliation behavior when heated again.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Clay Science - Volumes 105–106, March 2015, Pages 14–20
نویسندگان
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