کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1694690 | 1519084 | 2014 | 7 صفحه PDF | دانلود رایگان |

• A novel catalyst was developed from clay by treatment with KF.
• The treatment resulted in the formation of crystalline phase K2FeF4.
• Test of activity in the methanolysis of soybean oil for the synthesis of biodiesel
• Conversion rates of 99.7% were reached in reaction conditions considered mild.
• A basic catalyst with high stability was obtained.
A novel solid catalyst with basic properties was developed from untreated smectite chemically modified by treatment with potassium fluoride, resulting in a material with excellent stability and high catalytic activity in the conversion of soybean oil into biodiesel in the presence of methyl alcohol. The percentage of conversion into methyl esters of 99.7% was obtained under conditions of 1 h of reaction time at 338 K, 15 wt.% catalyst and molar ratio of methanol/oil of 6:1. A concomitant study was made to evaluate the effect of the mineralogical composition of the untreated clay on the properties of the catalysts and their performance in the transesterification reaction.
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Journal: Applied Clay Science - Volumes 91–92, April 2014, Pages 98–104