کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1731966 | 1521457 | 2015 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Biodiesel synthesis over millimetric γ-Al2O3/KI catalyst
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The use of spherical millimetric gamma-alumina (γ-Al2O3) as a catalyst support for the production of biodiesel from palm oil was demonstrated. The catalyst support was produced using dripping method, and KI catalyst was loaded on the support using impregnation method. The highest FAME (fatty acid methyl ester) yield of 98% was obtained when the reaction was carried out under the conditions of catalyst to oil ratio of 0.6 g (4wt.%, gcat./goil) using 0.24gKI/gγ-Al2O3 of catalyst loading, reaction time of 4 h, temperature of 60 °C and methanol to palm oil molar ratio of 14:1. XRD (X-ray diffraction) analysis showed the formation of K2O and KAlO2 phases on the KI/γ-Al2O3 catalyst which were possibly the active sites for the transesterification reaction. The highest number and strength of basic sites generated from the solid phase reaction of the KI/γ-Al2O3 catalyst loaded with 0.24 g kF/g γ-Al2O3 were confirmed by temperature programmed desorption of CO2 (CO2-TPD) analysis. The nitrogen adsorption-desorption isotherms was revealed a mesoporous structure of the catalysts. The leaching of potassium species in reused catalysts was observed, as verified by XRF (X-ray fluorescence). KI/γ-Al2O3 had a long life time and maintained sustained activity even after being repeatedly used for 11 cycles. The biodiesel yield was comparable to that produced from smaller catalysts. Thus, the catalyst could be potential for industrial use, as they can be handled safely, easily separated from the process fluid and used in fixed bed reactor to minimize pressure drop.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Energy - Volume 89, September 2015, Pages 965-973
Journal: Energy - Volume 89, September 2015, Pages 965-973
نویسندگان
Aminul Islam, Yun Hin Taufiq-Yap, Pogaku Ravindra, Siow Hwa Teo, S. Sivasangar, Eng-Seng Chan,