کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1790073 | 1524410 | 2015 | 6 صفحه PDF | دانلود رایگان |
• Cleavage behavior and single-crystal structure of MnTeMoO6 crystal were reported.
• Layered structure is the original of the cleavage in MnTeMoO6 crystal.
• MnTeMoO6 crystal can be made into micro device by stripping the cleavage layers.
Centimeter size crystals of MnTeMoO6 have been grown by the top-seeded solution growth method. The cleavage behavior and the single-crystal structure of MnTeMoO6 crystal were analyzed. The total charge density of MnTeMoO6 was calculated. Cleavage behavior analysis indicates that a perfect cleavage behavior with {001} planes was found in MnTeMoO6 crystal. Single crystal X-ray diffraction analysis reveals that the MnTeMoO6 single crystal crystallizes in the noncentrosymmetric tetragonal space group P 4¯21m (No. 113) with cell parameters a=5.269(3) Å, c=9.014(11) Å and Z=2, and exhibits a novel neutral two-dimensional layered structure consisting of asymmetric MnO4 tetrahedra, TeO4 polyhedra and MoO4 tetrahedra. The total charge density analysis indicates that these layers are held together by van der Waals forces and the natural cleavage planes lie between the two proximate neutral layers. The results show that the layered structure connected by the weak van der Waals forces is the original of the cleavage in MnTeMoO6 crystal, and MnTeMoO6 crystal can be made into micro nonlinear optical device by stripping the cleavage layers.
Journal: Journal of Crystal Growth - Volume 419, 1 June 2015, Pages 25–30