کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1790223 | 1524419 | 2015 | 5 صفحه PDF | دانلود رایگان |
• Thin films of phase pure Cu2O are grown on single crystal MgO substrates.
• MgO substrate orientation is important in achieving phase purity.
• Deposition with argon–oxygen plasma helps stabilize a single orientation.
Epitaxial growth of cuprous oxide (Cu2O) has been achieved on (1 0 0) and (1 1 0) orientations of MgO by plasma-assisted molecular beam epitaxy. Growth was investigated using a pure oxygen plasma as well as a 90%Ar/10%O2 plasma. Cu2O films grown using pure oxygen on MgO (1 0 0) have a limited growth window and typically exhibit multiple phases and orientations. Films grown on MgO (1 1 0) using pure oxygen are phase stable and predominantly (1 1 0) oriented, with some (2 0 0) orientation present. Films grown using an Ar/O2 plasma on MgO (1 0 0) have improved phase stability and a single (1 1 0) orientation. Growth on MgO (1 1 0) using an Ar/O2 plasma yields highly reproducible (1 1 0) oriented single phase Cu2O films with a much wider growth window, suggesting that this substrate orientation is preferable for Cu2O phase stability.
Journal: Journal of Crystal Growth - Volume 410, 15 January 2015, Pages 77–81