کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1809510 | 1525197 | 2014 | 5 صفحه PDF | دانلود رایگان |
The conductive polymers with unique nanostructures have attracted intense interest due to their potential application. Here the well-defined polypyrrole nanoparticles were facile fabricated via the facile chemical oxidative polymerization of pyrrole with high feeding ratio of phytic acid. Phytic acid is a renewable resource and a natural carbohydrate compound with a vast number of phosphate groups from plant which was used as the template and dopant for the nanostructured conductive polymer for the first time. The samples exhibit the well-defined nanoparticles observed by scanning electron microscope (SEM) and atomic force microscope (AFM). The PPy nanoparticles were achieved and outstanding electrical conductivity as high as 5263 S m−1 was obtained with the feeding mass ratio of phytic acid: pyrrole=3:7. Furthermore, the polypyrrole nanoparticles were characterized with Fourier transform infrared (FTIR), thermogravimetric analysis (TGA), and electrical conductivity techniques.
Journal: Physica B: Condensed Matter - Volume 449, 15 September 2014, Pages 181–185