کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1813777 1025640 2010 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Raman spectra and density of Li2O–B2O3–GeO2 glasses with high Li2O content
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Raman spectra and density of Li2O–B2O3–GeO2 glasses with high Li2O content
چکیده انگلیسی

One series of glass having the molar formula y[42.5Li2O·57.5GeO2]·(1−y)[42.5Li2O·57.5B2O3] where y ranged between 0 and 0.55 has been prepared and measured for density, molar volume and Raman spectra. No density anomaly was observed throughout the composition range of the studied glasses. The large difference in molecular mass between that of B2O3 and GeO2 is the reason for the density change. The linear change in density reveals that each oxide in the glass would contribute to the density by a specific factor. Alkali oxide is incorporated into the borate as well as the germanate networks. There are three essential Raman broad bands at ∼525, ∼775 and ∼835 cm−1. With increasing GeO2 content, the number of NBOs associated with Q2 decreases in the germanate network while three-membered rings of GeO4 tetrahedra are formed. The number of borate groups containing four coordinated boron decreases with increasing GeO2 content at the expense of B2O3.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica B: Condensed Matter - Volume 405, Issue 1, 1 January 2010, Pages 281–286
نویسندگان
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