کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1815022 | 1525254 | 2007 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: The structure of charge-compensated Fe3+ ions in ZnO The structure of charge-compensated Fe3+ ions in ZnO](/preview/png/1815022.png)
The properties of charge-compensated Fe3+ centers in hydrothermally grown ZnO single crystals were investigated by electron paramagnetic resonance (EPR) in X- and Q-band. The EPR angular dependences of the three types of Fe3+ centers were fitted using spin Hamiltonians appropriate for S =52 centers with Ci symmetry. The analysis of the results, and in particular the determination of the second rank fine structure tensors, suggests that Fe3+ substitutes Zn2+ with a significant distortion of the initial C3v symmetry of the Zn site. The centers are interpreted as Fe3+ substitutional on the Zn site with (i) an oxygen vacancy in one of the nearest non-axial anionic positions, (ii) a Zn vacancy in one of the six positions lying in the basal plane and (iii) a Zn vacancy in one of the nearest six cationic positions which form a trigonal prism.
Journal: Physica B: Condensed Matter - Volumes 401–402, 15 December 2007, Pages 382–385