کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
182855 | 459526 | 2016 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Novel configuration of polyimide matrix-enhanced cross-linked gel separator for high performance lithium ion batteries Novel configuration of polyimide matrix-enhanced cross-linked gel separator for high performance lithium ion batteries](/preview/png/182855.png)
• For the first time, a cross-linked gel polymer electrolyte with additional lithium ions, was introduced into a nonwoven separator.
• The PI nonwoven is employed to ensure enhanced thermal stability and mechanical strength of the IACS.
• With the introduction of PAMPS(Li+), the migration and mobility rate of anions could be hindered by the -SO3− group, giving rise to a high lithium ion transference number.
• This IACS is recommended as a promising candidate for the high-power and high-safety lithium ion batteries.
A novel composite nonwoven separator exhibiting high heat resistance, high ionic conductivity and high lithium ion transference number is fabricated by a simple dip-coating and heat treatment method. The thermal stable polyimide (PI) nonwoven matrix is chosen as a mechanical support and contributes to improving the thermal shrinkage of the composite nonwoven separator (abbreviated as IACS). The cross-linked poly(2-acrylamido-2-methylpropanesulfonic acid) PAMPS(Li+) gel polymer electrolyte (GPE), lithium ion sources of a single ion conductor, is introduced into the PI nonwoven matrix and acts as a functional filler. This PAMPS (Li+) GPE is proved to be able to provide internal short circuit protection, to alleviate liquid electrolyte leakage effectively, to supply more lithium ions dissociating from PAMPS (Li+) by liquid electrolyte solvent, to contribute a more stable interfacial resistance, and thus resulting in an excellent cyclability. More notably, the migration and mobility rate of anions could be hindered by the −SO3− group in the PAMPS (Li+) polymer based on electrostatic interaction, giving rise to a very high lithium ion transference number. These fascinating characteristics endow the IACS a great promise for the application in the high power and high safety lithium ion batteries.
Journal: Electrochimica Acta - Volume 204, 20 June 2016, Pages 176–182