کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
183041 459531 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Open Framework Allotropes of Silicon: Potential Anode Materials for Na and Li-ion Batteries
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Open Framework Allotropes of Silicon: Potential Anode Materials for Na and Li-ion Batteries
چکیده انگلیسی

We report a computational investigation of the potential of new open-framework allotropes of silicon as Na and Li-ion batteries. Most anode materials used in energy storage systems are characterized by a very high capacity but are very sensitive to the charge/discharge cycling. It is hence appealing to design a material with at the same time a good capacity and maintaining crystalline morphology upon multiple battery operation cycles. We investigated using electronic structure the capacity of a recently synthesized framework of silicon c-Si24 as an anode material and showed that the breaking of some Si-Si bonds leads to the formation of two new more flexible allotropes. We demonstrate that the major advantage of these allotropes is their reversible stable capacity that would sustain after several battery charge-discharge cycles.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 207, 20 July 2016, Pages 301–307
نویسندگان
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