کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
183647 459555 2015 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of high molecular flexibility polycarbonates for solid polymer electrolytes
ترجمه فارسی عنوان
سنتز پلی کربنات انعطاف پذیر مولکولی بالا برای الکترولیت پلیمرهای جامد
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


• A new polycarbonate was synthesized and showed a record-low Tg of −49.4 °C.
• Crosslinking provided mechanically stable polymer electrolyte films.
• Ionic conductivity up to 2 × 10−7 S cm−1 at room temperature was demonstrated.

A new self-plasticizing aliphatic polycarbonate comprising flexible alkyl and alkyl ether side groups was designed and synthesized from six-membered cyclic carbonate monomers with the aim of producing a material with high molecular flexibility (low Tg) and concomitant high ionic conductivity when used as a polymer electrolyte. The Tg of the novel polycarbonate was determined to be −49.4 °C at a molecular weight of 34 400 g mol−1, which is the lowest reported Tg to date for a substituted poly(trimethylene carbonate). UV-crosslinked polymer electrolytes were produced based on this novel material together with LiTFSI salt and showed ionic conductivities in the range of 2 × 10−8 to 2 × 10−7 S cm−1 at room temperature and 1 × 10−6 to 1 × 10−5 S cm−1 at 100 °C. The limited ionic conductivities of these electrolytes indicate that high molecular flexibility alone does not guarantee fast ion transport in solid polymer electrolytes and that other factors, such as the polarity of the polymer host material, will also influence the transport properties of the electrolyte.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 175, 1 September 2015, Pages 247–253
نویسندگان
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