کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
184566 459578 2015 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Tailoring of porous and nitrogen-rich carbons derived from hydrochar for high-performance supercapacitor electrodes
ترجمه فارسی عنوان
خیاطی از کربن غنی از متخلخل و نیتروژن مشتق شده از هیدروکلر برای اکسترودرهای با عملکرد بالا
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


• Carbons with various porous structures and nitrogen contents are produced from hydrochars.
• KOH plays an important role on the creation of porous structures and selective production of active pyridinic and pyrrolic nitrogen species.
• The highest specific capacitance reaches 492 F g−1 in H2SO4 electrolyte and 279 F g−1 in KOH electrolyte.
• The excellent electrochemical properties depend on the synergistic effect of N-doped nature and porous structures.

Biomass-derived hydrochar (HC) was used as the precursor to synthesize porous and nitrogen-rich carbons for supercapacitor electrodes. Porous carbon (HC/KOH) activated by potassium hydroxide was used to prepare nitrogen-rich porous carbon (HC/KOH/N) by subsequent calcination in melamine. Similarly, HC/N/KOH was obtained from nitrogen-rich carbon (HC/N) calcined in melamine by subsequent KOH activation. It is found that KOH plays an important role on the creation of porous structures and selective production of active pyridinic and pyrrolic nitrogen species. HC/KOH samples with abundant pores are excellent as supercapacitor electrodes in basic medium, whereas HC/N/KOH samples enriched with nitrogen functionalities are especially applicable in acidic medium. Typically, HC/KOH and HC/N/KOH show the highest specific capacitance of 279 and 492 F g−1 at the current density of 0.1 A g−1 in KOH and H2SO4 electrolytes, respectively. Their specific energy density and power density are up to 8.1–12 Wh kg−1 and about 24 W kg−1 at 0.05 A g−1 in two-electrode cell. The excellent electrochemical properties of as-made carbons may be attributed to the high specific surface (1197 m2 g−1) for the former, and to the synergistic effect of combined accessible specific surface area (566 m2 g−1) and doped nitrogen (4.38 wt.%) for the latter. This research provides a new routine for the development of high-performance electrochemical supercapacitors with carbonaceous electrodes derived from biomass precursors.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 155, 10 February 2015, Pages 201–208
نویسندگان
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